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Dual effect of pH and X-ray irradiation on properties of gelatin/trans-cinnamaldehyde-based composite films for sustainable packaging

Jaiswal, Lily; Shankar, Shiv et Lacroix, Monique ORCID logoORCID: https://orcid.org/0000-0002-2042-4033 (2024). Dual effect of pH and X-ray irradiation on properties of gelatin/trans-cinnamaldehyde-based composite films for sustainable packaging International Journal of Biological Macromolecules , vol. 280 , nº 135652. pp. 1-11. DOI: 10.1016/j.ijbiomac.2024.135652.

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Résumé


Gelatin (Gel) based water-insoluble films with antimicrobial properties were developed by the green method using trans-cinnamaldehyde (TCA) and low-energy X-ray irradiation as dual crosslinkers. The Gel/TCA composite films (GTCF) were prepared at different pH (4, 6, 8, and 10) and crosslinked by incorporating 5 % (w/w, based on Gel) TCA and X-ray irradiation (350 kV and 11.4 mA) with doses of 0, 5, 10 and 15 kGy. The presence of TCA in GTCF forms dense, flexible, and strong films when exposed to X-ray irradiation. The GTCF at pH 6, incorporated with 5 wt% TCA and irradiated with 10 kGy X-ray, displayed the highest degree of crosslinking (DOC) (93.4 ± 3.4 %), tensile strength, excellent UV-barrier (> 99.9 %), antimicrobial (inhibitory capacity of >50 %), and water vapor permeability (4.1 ± 0.6 g.mm/m2.day. kPa), and low solubility in water (0.5 ± 0.3 %), and oxygen permeability. The GTCF, crosslinked with X-ray irradiation, has multifunctional properties and strong potential in the sustainable packaging industry to augment the shelf life of food and reduce food waste. To the best of our information, this is the first and novel report investigating the effects of pH on the properties of GTCF crosslinked with X-ray.

Type de document: Article
Mots-clés libres: Gelatin; Trans-cinnamaldehyde; X-ray irradiation; Cross-linking; Antimicrobial activity
Centre: Centre INRS-Institut Armand Frappier
Date de dépôt: 23 sept. 2024 19:17
Dernière modification: 23 sept. 2024 19:17
URI: https://espace.inrs.ca/id/eprint/15973

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