Khan, Ruhul A.; Salmieri, Stéphane; Dussault, Dominic; Uribe-Calderon, Jorge; Kamal, Musa R.; Safrany, Agnes et Lacroix, Monique ORCID: https://orcid.org/0000-0002-2042-4033
(2010).
Production and properties of nanocellulose-reinforced methylcellulose-based biodegradable films
Journal of Agricultural and Food Chemistry
, vol. 58
, nº 13.
pp. 7878-7885.
DOI: 10.1021/jf1006853.
Résumé
Methylcellulose (MC)-based films were prepared by casting from its 1% aqueous solution containing 0.5% vegetable oil, 0.25% glycerol, and 0.025% Tween 80. Puncture strength (PS), puncture deformation (PD), viscoelasticity coefficient, and water vapor permeability (WVP) were found to be 147 N/mm, 3.46 mm, 41%, and 6.34 g.mm/m(2).day.kPa, respectively. Aqueous nanocellulose (NC) solution (0.1-1%) was incorporated into the MC-based formulation, and it was found that PS was improved (117%) and WVP was decreased (26%) significantly. Films containing 0.25% NC were found to be the optimum. Then films were exposed to gamma radiation (0.5-50 kGy), and it was revealed that mechanical properties of the films were slightly decreased after irradiation, whereas barrier properties were further improved with a decrease of WVP to 28.8% at 50 kGy. Molecular interactions due to incorporation of NC were supported by FTIR spectroscopy. Thermal properties of the NC-containing films were improved, confirmed by TGA and DSC. Crystalline peaks appeared due to NC addition, found by XRD. Micrographs of films containing NC were investigated by SEM.
| Type de document: | Article |
|---|---|
| Mots-clés libres: | - |
| Centre: | Centre INRS-Institut Armand Frappier |
| Date de dépôt: | 30 juin 2024 21:30 |
| Dernière modification: | 30 juin 2024 21:30 |
| URI: | https://espace.inrs.ca/id/eprint/14789 |
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