Tran, Lan Huong; Drogui, Patrick; Mercier, Guy et Blais, Jean-François 
ORCID: https://orcid.org/0000-0003-3087-4318
(2010).
Comparison between Fenton oxidation process and electrochemical oxidation for PAH removal from an amphoteric surfactant solution.
Journal of Applied Electrochemistry
, vol. 40
, nº 8.
pp. 1493-1510.
DOI: 10.1007/s10800-010-0128-4.
Résumé
The decomposition of polycyclic aromatic hydrocarbons in a creosote oily solution and in synthetic solutions containing naphthalene and pyrene was investigated in the presence of an amphoteric surfactant using electrooxidation by comparison to Fenton oxidation process. Electrolysis was carried out using a parallelepipedic electrolytic 1.5-L cell containing five anodes (expanded titanium covered with ruthenium) and five cathodes (stainless steel) alternated in the electrode pack, whereas Fenton oxidation process was carried out in 500 mL Erlenmeyer glass-flasks in which H2O2 and Fe2+ were added. Using electrochemical oxidation, the sum concentration of 16 polycyclic aromatic hydrocarbons investigated could be optimally diminished by up to 80–82% by applying a current density of 9.23 mA cm−2 and a pH of 4.0 or 7.0 for 90-min reaction period. By comparison, the best yield (46%) of Fenton oxidation process for polycyclic aromatic hydrocarbons degradation was recorded by using H2O2/Fe2+ molar ratio of 11.0 and a pH of 4.0.
| Type de document: | Article |
|---|---|
| Mots-clés libres: | polycyclic aromatic hydrocarbon; electrochemical degradation; Fenton oxidation; hydroxyl radical; ruthenium oxide electrode; Surfactant |
| Centre: | Centre Eau Terre Environnement |
| Date de dépôt: | 11 janv. 2021 15:43 |
| Dernière modification: | 18 févr. 2022 20:04 |
| URI: | https://espace.inrs.ca/id/eprint/10675 |
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